Di-, tri- and tetrafunctional methyl isobutyl and methyl amyl ketoxime-based silanes

ABSTRACT

The invention relates to the following novel silanes: methyl vinyl bis(methyl isobutyl ketoximino) silane; methyl vinyl bis-(methyl amyl ketoximino) silane; methyl tris-(methyl isobutyl ketoximino) silane; vinyl tris-(methyl isobutyl ketoximino) silane; methyl tris-(methyl amyl ketoximino) silane; vinyl tris-(methyl amyl ketoximino) silane; tetrakis-(methyl isobutyl ketoximino) silane; tetrakis-(methyl amyl ketoximino) silane methoxy tris-(methyl isobutyl ketoximino) silane; ethyl tris-(methyl isobutyl ketoximino) silane; ethoxy tris-(methyl isobutyl ketoximino) silane; methoxy tris-(methyl amyl ketoximino) silane; ethyl tris-(methyl amyl ketoximino) silane; ethoxy tris-(methyl amyl ketoximino) silane; and mixtures thereof.

This application is a continuation-in-part of U.S. patent applicationSer. No. 07/947,015, filed Sep. 17, 1992, which is incorporated hereinby reference, now U.S. Pat. No. 5,359,108.

BACKGROUND OF THE INVENTION

A variety of useful silicone compositions cure at room temperature toelastomeric materials which possess a broad spectrum of physical andchemical properties. These compositions are particularly desirablebecause they surface cure in thirty minutes or less after exposure tothe atmosphere but remain substantially soft for years. They also adheretenaciously to a wide variety of materials such as glass, porcelain,wood, metal and organic plastics. Because of this, they are adaptablefor practically any type of sealant application including building andautomotive equipment applications. The following patents discuss some ofthese compounds in more detail.

U.S. Pat. No. 3,189,576 to Sweet describes oxime silanes useful in themanufacture of room temperature curing compositions. Specifically, Sweetteaches trifunctional and tetrafunctional ketoximino silanes ascrosslinkers and their use in the manufacture of room temperature curingsilicone elastomeric compositions by mixing them with hydroxylendblocked polydiorganosiloxanes. These compositions can also containfillers and curing catalysts.

U.S. Pat. No. 4,503,210 to Von Au discloses mixtures of tri- andtetrafunctional ketoximino silanes and focuses specifically on theusefulness of tetrafunctional ketoximino silanes in sealantformulations.

The problem with known tetrafunctional oximino silanes (i.e., e.g.,those based on methyl ethyl ketoxime (MEKO) and acetone oxime) is thatthey are solids at room temperature. Since such compounds are verysensitive to moisture they decompose easily to semisolids which aredifficult to handle. Thus, these materials have a poor shelf life andrequire special care in their packaging and transporting.

The known tetrafunctional and trifunctional oximino silanes (i.e., e.g.,those based on MEKO and acetone oxime) have other drawbacks.Traditionally, when these materials have been combined with siliconepolymers the resulting product has been opaque. This has substantiallylimited the applications in which these materials can be used.

As the applications in which room temperature curing compositions can beutilized continue to increase, the specific kinds of properties requiredof these compositions continue to change. The art is continually lookingfor room temperature curing compositions having new desirable propertieswithout the old undesirable properties like opacity and physical statelimitations (solids). We have surprisingly discovered that the silanesof the invention satisfy this need in the art.

DESCRIPTION OF THE INVENTION

The invention relates to silanes of the formula: (R'R"C=NO)_(a)SiR1_(4-a) where R' is any saturated straight chain or branched alkylradical of 3 to 7 carbon atoms such as propyl, isopropyl, butyl,isobutyl and amyl; R" is methyl; and R1is any saturated, straight chainalkyl or alkoxy radical of 1 to 8 carbon atoms such as methyl, ethyl andpropyl or an alkenyl radical of 1 to 5 carbon atoms such as methyl,vinyl and allyl and a is a positive integer ranging in value from 2 to4. More specifically, the invention relates to the following silanes:methyl vinyl bis(methyl isobutyl ketoximino) silane; methyl vinylbis-(methyl amyl ketoximino) silane; methyl tris-(methyl isobutylketoximino) silane; vinyl tris-(methyl isobutyl ketoximino) silane;methyl tris-(methyl amyl ketoximino) silane; vinyl tris-(methyl amylketoximino) silane; tetrakis-(methyl isobutyl ketoximino) silane;tetrakis(methyl amyl ketoximino) silane; methoxy tris-(methyl isobutylketoximino) silane; ethyl tris-(methyl isobutyl ketoximino) silane;ethoxy tris-(methyl isobutyl ketoximino) silane; methoxy tris-(methylamyl ketoximino) silane; ethyl tris(methyl amyl ketoximino) silane;ethoxy tris-(methyl amyl ketoximino) silane; and mixtures thereof.

In a preferred embodiment, the ketoxime silanes are selected frommethoxy tris-(methyl isobutyl ketoximino) silane; ethoxy tris-(methylisobutyl ketoximino) silane; methoxy tris-(methyl amyl ketoximo) silane;and ethoxy tris-(methyl amyl ketoximo) silane. In another preferredembodiment, the ketoxime silane is a mixture of tetrakis-(methylisobutyl ketoximino) silane and at least one of methoxy tris-(methylisobutyl ketoximino) silane; ethoxy tris-(methyl isobutyl ketoximino)silane; methoxy tris-(methyl amyl ketoximino) silane; ethoxytris-(methyl amyl ketoximino) silane methyl tris-(methyl isobutylketoximino)silane and methyl tris-(methyl amyl ketoximino) silane. Aone-component room-temperature-curing-system may be prepared by reactinga silane of the above formula with a hydroxy-endblocked siloxane polymerin the substantial absence of moisture. In another preferred embodimentof the invention, in the ketoxime silanes of the above formula, R1 has 1to 5 carbon atoms.

As currently used in sealant compounding, commercial tetra-functionaloximino silanes are either mixed (dissolved) in trifunctional oximinosilanes as described in U.S. Pat. No. 4,503,210 or dissolved in organicsolvents.

In the former case solubility limits the level of tetrafunctionaloximino silane in the trifunctional oximino silane to 35-40% at roomtemperature. This is disadvantageous because higher levels oftetrafunctional oximino silane increase cure rate and minimize (if noteliminate) the need for a catalyst.

In the latter case, solid tetrafunctional oximino silanes are mixed withhydrocarbons like toluene, benzene and xylene, organic ethers likediethylether and dibutylether, ketones and halogenated solvents tofacilitate ease of handling in applications which require preciseamounts of tetrafunctional oximino silane. Because some of thesesolvents are flammable and carcinogenic, further precautions must betaken to ensure the satiety of personnel during processing. In addition,one must ensure that the vapor emissions from the finished sealantproducts generated during end use are safe :for people and theenvironment. These precautions are both costly and time consuming.

Solubility is also a concern. That is, for example, at room temperature,tetrafunctional MEKO-based silane is only 50% soluble in toluene and inmethyl ethyl ketoxime, 40% soluble in diethyl ether and 10% soluble indibutyl ether. As a result, significant amounts of solvent may berequired in the formulation. In addition, crystallization can occur atlower temperatures (i.e., e.g., during shipping in winter months) and athigher concentrations of the tetrafunctional oximino silane.

Because of this, there has been a long felt need in the industry fortetrafunctional oximino silanes which do not require organic solvents ormixing with trifunctional oximino silanes. We have surprisinglydiscovered that the novel tetrakis oximino silanes of our invention,e.g. tetrakis-(methyl isobutyl ketoximino) silane and tetrakis-(methylamyl ketoximino)silane are liquids and thus do not suffer with the sameproblems as their solid counterparts. These new silanes offer theability to employ solvent-free formulations, if not significantlydecrease solvent content in the composition. In addition, there is addedflexiblity and simplification when formulating room temperaturemoisture-curable silicone compositions. Because the new silanes areliquid tetrafunctional oximino silanes, one can add more of thesesilanes to increase the cure rate of the composition. The amount ofother tetrafunctional oximino silanes which can be used in this type ofsilicone composition is limited by their solubility in the solvent.

That the novel tetrafunctional oximino silanes are liquid is surprisingsince generally, physical states of organic compounds transform from gasto liquid to solid as molecular weight increases in a homologous series.See, R. T. Morrison and R. N. Boyd, Organic Chemistry, 91-4 (5th Ed.1987). For example, in the aliphatic hydrocarbon series, lower molecularweight compounds like propane (MW 44) and butane (MW 58) are gases,higher molecular weight hydrocarbons like hexane (MW 86) and octane (MW114) are liquids and the long chain hydrocarbon paraffins like eicosane(MW 282.6), docosane (MW 316.6) and tetracosane (MW 338.7) are solids.

In the instant case, since tetrafunctional oximino silanes of lowermolecular weight alkyl ketoximes like acetone oxime (MW 73) and methylethyl ketoxime (MW 87) are solids, we also expected tetrafunctionaloxime silanes of methyl isobutyl ketoxime and methyl amyl ketoxime whichhave higher molecular weights (115 and 129 respectively) to be solids.However, surprisingly, we discovered that both the tetrafunctionaloximino silanes of the invention, are liquids at room temperature.

In addition to the novel liquid tetrafunctional oximino silanes, we havealso discovered unexpectedly, that when oximino silanes (tetra-oximino,tris-oximino or bis-oximino) of the invention are formulated withhydroxyl terminated polydimethylsiloxane (HTPDMS), a well known siliconepolymer, an optically clear silicone rubber results. This is surprisingbecause generally when commercially available oxime silanes have beencombined in typical and useful concentrations with silicone polymers, avery cloudy and opaque rubber results. (Compare Examples 1-9 withComparative, Examples 1-4 below). This has limited the number ofapplications in which these materials can be utilized. In light of ourdiscovery, the door is now open to a variety of applications in whichaesthetics are important and from which oxime silanes have traditionallybeen excluded.

The novel ketoximino silanes of the invention may be prepared byfollowing the syntheses outlined below. See, U.S. Pat. No. 4,400,527.Alternately, they may be prepared by any means known in the art. We notethat the oximes used in the syntheses below may be prepared by any meansknown in the art. See, for example, the syntheses outlined in U.S. Pat.Nos. 4,163,756 and 3,991,115 both to Allied-Signal Inc.

The novel silanes of this invention can be used in combination withother crosslinking agents, which include other oximino silanes as wellas alloxy silanes and alkoxy-oximino silanes. Examples of such silanesare dislosed in the following publications: U.S. Pat. Nos. 3,697,568;3,896,079; 4,371,682 and 4,657,967.

Preparation of tetrakis-(methyl isobutyl ketoximino) silane.

A 1 liter 3-necked flask equipped with a condenser, thermometer anddropping funnel was charged with 350 ml of hexane and 96.7 g (0.84 mol)of distilled methyl isobutyl ketoxime. A drierite tube was attached tothe condenser to ensure a dry reaction medium. The reaction flask wasthen placed in a cold water bath. While the hexane/ketoxime solution wasstirred using a magnetic stirrer, 17 g (0.1 mol) tetrachloro silane wasadded dropwise into the reaction flask. The reaction temperature wasmaintained between 35° and 42° C. during the addition. After theaddition of tetrachloro silane was complete, the reaction mixture wasstirred for 5 minutes and then allowed to settle for 5 minutes. Thecolorless hexane solution top phase was separated from the viscousmethyl isobutyl ketoxime hydrochloride bottom phase using a separatoryfunnel. The top phase was then treated with anhydrous ammonia gas from acylinder for 10 minutes. The solid ammonium chloride that separated outwas filtered off and the colorless filtrate was subjected todistillation under reduced pressure (50° C. at 5 mm Hg) on a rotovap toremove hexane. About 42 g (8.6%) yield) of a colorless liquid wasobtained. The identity of this material as tetrakis-(methyl isobutylketoximino) silane was confirmed by proton and carbon-13 NMR and GC/Massspectral data.

Preparation of tetrakis-(methyl amyl ketoximino) silane.

A 2 liter three-necked round bottom flask, fitted with an additionfunnel, condenser and thermometer, was charged with 1300 ml of hexaneand 418.6 g (3.24 mol) of methyl amyl ketoxime. While the solution wasbeing stirred by means of an overhead stirrer, 67.96 g (0.4 mol) oftetrachloro silane was added dropwise over a period of 30 minutes duringwhich time the reaction temperature was kept between 37°-42° C. Afterthe tetrachloro silane had been added, the reaction mixture was allowedto stand for five minutes. The cloudy top phase was separated from themethyl amyl ketoxime hydrochloride bottom phase using a separatoryfunnel. Then, the top phase was neutralized with anhydrous ammonia overa period of 15 minutes and the solid ammonium chloride produced wasfiltered off. The hexane was removed from the filtrate under vacuum togive 178.5 g (82.6%) of a liquid. The identity of this liquid wasconfirmed as tetrakis-(methyl amyl ketoximino) silane by IR and protonand carbon-13 NMR spectral data.

PREPARATION OF ALKOXY-OXIMINO SILANES MIXTURE

Reaction of tetrachlorosilane:ethanol:methyl amyl ketoxime at 1:1:7 moleratio:

A 1 liter 3-necked flask equipped with a condenser, dropping funnel andreflux condenser fitted with a drying tube was charged with 348 gms ofhexane, 11.5 g (0.25 mol) of ethanol and 232.2 g (1.80 molt) ofdistilled methyl amyl ketoxime. While the alcohol, oxime and hexanesolution was stirred using a overhead mechanical stirrer, 42.5 g (0.25mol) of tetrachlorosilane was added dropwise into the reaction flask.During the addition, the reaction temperature was maintained between 35°and 42° C. After the addition of tetrachlorosilane was completed, thereaction mixture was stirred for 5 minutes and then allowed to settlefor 5 minutes. The top phase was separated from the viscous methyl amylketoxime hydrochloride bottom phase using a separatory funnel. The topphase was neutralized with ammonia gas from a cylinder for 10 minutes.The precipitated ammonium chloride solid was separated by filteration.The clear colorless filterate was stripped of hexane to give 94.0 g of acolorless liquid. Gas chromatographic analysis of the liquid showed thatit contained triethoxy(methyl amyl ketoximino) silane (5.6%),diethoxybis(methyl amyl ketoximino) silane (12.5%), ethoxytris(methylamyl ketoximino) silane (43.2%), tetrakis (methyl amyl ketoximino)silane (33.9%) and methyl amyl ketoxime (4.5%). The identify of thesesilanes were confirmed by GC-mass spec analysis.

Preparation of methyl tris-(methyl isobutyl ketoximino) silane.

A 5 liter, three-necked and water jacketed flask, fitted withthermometer, overhead stirrer and addition funnel, was charged with714.3 g (6.20 mol) of methyl isobutyl ketoxime and 3000 ml of hexane.One mole or 149.48 g of methyltrichlorosilane was added dropwise over aperiod of 1 hour during which the reaction temperature was maintainedbetween 37°-42° C. After the addition of methyltrichlorosilane wascomplete, the reaction mixture was stirred for 5 minutes and allowed tostand for 10 minutes. The told phase was separated from the methylisobutyl ketoxime hydrochloride bottom phase using a separatory funneland neutralized with ammonia gas by bubbling the ammonia through theliquid for 10 minutes. Solid ammonium chloride was filtered off andhexane was removed from the filtrate by vacuum distillation to give 380g (98.7%) of a colorless liquid. The identity of the product as methyltris-(methyl isobutyl ketoximino) silane was confirmed by IR and protonand carbon-13 NMR spectral data.

Preparation of vinyl tris-(methyl isobutyl ketoximino) silane.

A 3 liter, three-necked, round bottomed flask equipped with an overheadstirrer, thermometer and addition funnel was charged with 714.0 g (6.20mol) of methyl isobutyl ketoxime and 1200 ml of hexane. While stirring,161.5 g (1.0 mol) of vinyltrichlorosilane was added dropwise over aperiod of 1 hour and the reaction temperature was maintained between37°-41° C. After the addition was complete, the reaction mixture wasallowed to stand for 10 minutes. The top phase containing product andhexane was separated from the bottom phase (methyl isobutyl ketoximehydrochloride) using a separatory funnel and neutralized with ammoniagas for 10-15 minutes. Solid ammonium chloride was filtered off andhexane was removed from the filtrate by distilling under reducedpressure to give 374 g (94%) of a colorless liquid. The identity of thisliquid as vinyl tris-(methyl isobutyl ketoximino) silane was confirmedby IR and proton and carbon-13 NMR spectral data.

Preparation of methyl tris-(methyl amyl ketoximino) silane.

A 2 liter, three-necked, round bottomed flask, fitted with athermometer, overhead stirrer and addition funnel was charged with 394.1g (3.05 mol) of methyl amyl ketoxime and 1000 ml of hexane. Whilestirring the contents in the flask, 74.5 g (0.5 mol) ofmethyltrichlorosilane was added dropwise from the addition funnel over aperiod of 30 minutes. During the addition, the reaction temperature wasmaintained at 35°-41° C. After the addition was complete, the reactionmixture was allowed to stand for 10 minutes. The top phase containinghexane and the product was separated from the heavy methyl isobutylketoxime hydrochloride bottom phase using a separatory funnel. The topphase was neutralized with ammonia gas by bubbling the ammonia throughthe liquid for 10 minutes. Solid ammonium chloride was filtered off andhexane was removed from the filtrate by distillation under reducedpressure to give 201.8 g (94.5%) of a colorless liquid. This liquid wasidentified by IR and proton and carbon 13 NMR spectral data as methyltris-(methyl amyl ketoximino) silane.

Preparation of vinyl tris-(methyl amyl ketoximino) silane.

A 2 liter, three-necked flask fitted with overhead stirrer, additionfunnel and thermometer was charged with 236.4 g (1.83 mol) of methylamyl ketoxime and 800 ml of hexane. While the contents of the flask werestirred, 48.45 g (0.3 mol) of vinyl-trichlorosilane was added dropwise,from the addition funnel over a period of 30 minutes during which thereaction temperature was maintained between 32°-41° C. After theaddition of vinylchlorosilane was complete, the reaction mixture wasallowed to stand for 10 minutes. The top phase containing product andhexane was separated from the heavy bottom phase (methyl amyl ketoximehydrochloride) using a separatory funnel and neutralized with ammoniagas by bubbling the ammonia through the liquid for 10 minutes. Ammoniumchloride was filtered to give a clear filtrate. Hexane was removed fromthe filtrate by distilling under reduced pressure to give 115 g (87%) ofa colorless liquid which was identified as vinyl tris-(methyl amylketoximino) silane by IR and proton and carbon-13 NMR spectral data.

Preparation of methyl vinyl bis-(methyl isobutyl ketoximino) silane

Into a 500 ml, three-necked flask, fitted with thermometer, condenserand dropping funnel, was charged a solution of 47.17 g (0.41 mol) ofmethyl isobutyl ketoxime and 250 ml of hexane. While stirring thismixture by means of a magnetic stirrer, 14.11 g (0.1 mol) of methylvinyl dichlorosilane was added dropwise from the addition funnel over aperiod of 15 minutes. The reaction temperature was maintained between33°-38° C. After the addition of chlorosilane was complete, the reactionmixture was allowed to stand for 5 minutes during which the phasesseparated. The top phase was separated from the oxime hydrochloridebottom phase by means of a separatory funnel. The top phase wasneutralized with ammonia gas by bubbling the ammonia through the liquidfor 10 minutes and the precipitated ammonium chloride was filtered off.Hexane from the filtrate was removed by distillation under reducedpressure to give 27.5 g (89%) of a colorless liquid which was identifiedas methyl vinyl bis-(methyl isobutyl ketoximino) silane by IR and protonand carbon-13 NMR spectral data.

Preparation of methyl vinyl bis-(methyl amyl ketoximino) silane

A 3 liter, three-necked flask fitted with an overhead stirrer, additionfunnel and thermometer was charged with 529 g (4.1 mol) of methyl amylketoxime and 1200 ml of hexane. While stirring the contents of theflask, 141 g (1.0 mol) of methyl vinyl dichlorosilane was added dropwisefrom the addition funnel over a period of 40 minutes during which thereaction temperature was maintained between 28°-32° C. After theaddition was complete, the reaction mixture was allowed to stand for 10minutes to form two phases. The top phase containing product and hexanewas removed from the oxime hydrochloride heavy phase using a separatoryfunnel and neutralized with ammonia gas by bubbling the ammonia throughthe liquid for 10 minutes. Ammonium chloride solid was filtered andhexane was removed from the filtrate by distillation under reducedpressure to give 286 g (87.7%) of a colorless liquid. This liquid wasidentified as methyl vinyl bis(methyl amyl ketoximino) silane by IR andproton and carbon-13 NMR spectral data.

EXAMPLE 1

To a 100 ml beaker was added 50 parts by weight of hydroxyl terminatedpolydimethylsiloxane (HTPDMS) having a viscosity of 50,000 cst. Then,1-4 parts by weight of methyl tris-(methyl isobutyl ketoximino) silane(prepared in accordance with the synthesis disclosed herein) was added.The compounds were mixed at 25° C. at 200 rpm using a standardlaboratory stirrer for 5 minutes. The resulting product cured to a clearsilicone robber.

EXAMPLE 2-9

The experiment outlined in Example 1 above, was repeated using thefollowing silanes:

1.) 1-4 parts by weight methyl tris-(methyl amyl ketoximino) silane;

2.) 2-3 parts by weight vinyl tris-(methyl amyl ketoximino) silane;

3.) 2-3 parts by weight vinyl tris-(methyl isobutyl ketoximino silane);

4.) 1-3 parts by weight tetrakis-(methyl amyl ketoximino) silane;

5.) 1-3 parts by weight tetrakis-(methyl isobutyl ketoximino) silane;

6.) 3:1 parts by weight of a mixture of methyl tris-(methyl isobutylketoximino) silane and tetrakis-(methyl isobutyl ketoximino) silane;

7.) 3:1 parts by weight of a mixture of methyl tris-(methyl amylketoximino) silane and tetrakis-(methyl amyl ketoximino) silane;

8.) 3:1 parts by weight of a mixture of methyl tris-(methyl amylketoximino) silane and tetrakis-(methyl isobutyl ketoximino) silane; Theresults were the same as those reported in Example 1. That is, theresulting cured silicone rubber was clear.

Comparative Example 1

To a 100 ml beaker was added 50 parts by weight of HTPDMS, having aviscosity of 50,000 cst. Then, 3-4 parts by weight of methyltris-(methyl ethyl ketoximino) silane was added. The compounds weremixed at 25° C. and 200 rpm using a standard laboratory stirrer for 5minutes. The resulting product cured to an opaque, cloudy siliconerubber.

Comparative Examples 2-4

The procedure outlined in Comparative Example 1 was repeated using thefollowing silanes:

1.) 2-10 parts by weight vinyl tris-(methyl ethyl ketoximino) silane;

2.) 3-10 parts by weight tetrakis-(methyl ethyl ketoximino) silane intoluene;

3.) 3:1 parts by weight of a mixture of methyl tris-(methyl ethylketoximino) silane and tetrakis-(methyl ethyl ketoximino) silane. Theresults are the same as those reported for Comparative Example 1. Thatis, the resulting product cured to an opaque, cloudy silicone rubber.

The silanes of the invention have utility as intermediates in thepreparation of various one-component room-temperature-curingcompositions for sealant, adhesive, coating and other silicone polymerapplications. These one-component systems may be prepared in accordancewith the teachings of U.S. Pat. No. 3,189,576 to Sweet (Example 17 atcol. 12, lines 6-26) and U.S. Pat. No. 4,720,530 to Wurminghause et al.at col. 1, lines 60-67 and col. 2, lines 1-43 which disclosure is herebyincorporated herein by reference. Generally, the method for preparingone-component room-temperature-curing compositions comprises reacting inthe substantial absence of moisture a hydroxy-endblocked siloxanepolymer with a silane. Optionally, fillers such as silica, chalk andglass beads, adhesion promotors such as organofunctional silanes andcatalysts such as tin carboxylates, dibutyl tin diacetate, and dibutyltin dilaurate, lead carboxylates, zinc carboxylates and organo titanatesmay be included in these formulations.

What is claimed:
 1. Ketoxime silanes of the formula:(R'R"C=NO)_(a)SiR1_(4-a) where R' is any saturated straight chain or branched alkylradical of 3 to 7 carbon atoms; R" is methyl; and R1 is any alkoxyradical of 1 to 8 carbon atoms and a is a positive integer ranging invalue from 2 to
 4. 2. Ketoxime silanes of claim 1 wherein R' is selectedfrom propyl, isopropyl, butyl, isobutyl and amyl.
 3. Ketoxime silanes ofclaim 1 wherein the silanes are selected from:methoxy tris-(methylisobutyl ketoximino) silane; ethoxy tris(methyl isobutyl ketoximino)silane; methoxy tris-(methyl amyl ketoximino) silane; ethoxytris-(methyl amyl ketoximino) silane; and mixtures thereof.
 4. Theketoxime silanes of claim 1 wherein said silane is selected from methoxytris-(methyl isobutyl ketoximino) silane and ethoxy tris-(methylisobutyl ketoximino) silane.
 5. The ketoxime silanes of claim 1 whereinsaid silane is selected from methoxy tris-(methyl amyl ketoximo) silaneand ethoxy tris-(methyl amyl ketoximo) silane.
 6. The ketoxime silanesof claim 1 wherein said silane is a mixture of tetrakis-(methyl isobutylketoximino) silane and at least one of methoxy tris-(methyl isobutylketoximino) silane and ethoxy tris-(methyl isobutyl ketoximino) silane.7. The ketoxime silanes of claim 1 wherein said silane is a mixture oftetrakis-(methyl isobutyl ketoximino) silane and at least one of methoxytris-(methyl amyl ketoximino) silane and ethoxy tris-(methyl amylketoximino) silane.
 8. The ketoxime silanes of claim 1 wherein R1 has 1to 5 carbon atoms.